Indirect analysis of corticosteroids. 5. The determination of 17-deoxycorticosteroids.

نویسندگان

  • D EXLEY
  • S C INGALL
  • J K NORYMBERSKI
  • G F WOODS
چکیده

(III) from (I) and of 21-norpregnan-20-als (IV) from (II) (Brooks & Norymberski, 1953). The last conversion was presumed; it is now established by the isolation of 3,-hydroxy-21-norpregn-5-en-20-al (VI) (as its acetate) from the reaction of pregn-5ene-3f:20fl:21-triol (V) with sodium bismuthate. Reduction with borohydride followed by oxidation with sodium bismuthate was expected to convert 20:21-ketols (I) into C-20 aldehydes (IV) as well. In

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عنوان ژورنال:
  • The Biochemical journal

دوره 81  شماره 

صفحات  -

تاریخ انتشار 1961